Product ID:O-PHENANTHROLINE FERROUS SULFATE COMPLEX
MSDS Date:08/11/1989
FSC:6810
NIIN:00F020823
MSDS Number: BMKKR

FISHER SCIENTIFIC CHEMICAL DIV

1 REAGENT LANE
FAIR LAWN, NJ 07410-2802

Emergency Phone: (201) 796-7100 OR (201) 796-7523

Info Phone: (201) 796-7100 OR (201) 796-7523

Preparer: GASTON L. PILLORI

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

1,10-PHENATHROLINE, MONOHYDRATE, 4,5-PHENANTHROLINE

CAS: 5144-89-8

RTECS: SF8437000

Fraction By Weight: 1.2%

FERROUS SULFATE, HEPTAHYDRATE

CAS: 7782-63-0

RTECS: NO8510000

Fraction By Weight: 1.2%

ACGIH TLV: 1 MG/CUM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER, H2O

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 97%

LD50 LC50 Mixture:ORAL TDLO (WOMAN): 600 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITATION. SKIN: DERMATITIS. EYES: CONJUNCTIVITIS. INGESTION:
HEARTBURN/METALLIC TASTE IN MOUTH/NAUSEA/UPPER GASTRIC
DISCOMFORT/CONSTIPATION/DIARRHEA/POISONING/VOMITUS M AY BE
BLOODY/DEHYDRATION/MUCOUS MEMBRANE
IRRITATION/LIVER/KIDNEY/CIRCULATORY/CARDIOVASCULAR/CNS
EFFECTS/SHOCK/PALLOR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: RESPIRATORY TRACT IRRITATION. SKIN:
DERMATITIS. EYES: CONJUNCTIVITIS. INGESTION: HYPOTENSION/PULMONARY
CHANGES W/DYSPNEA/MENTAL CONFUSION/CONVULSIONS/CIRCULATORY
COLLAPSE/HEPATIC FAILURE W /JAUNDICE/BLEEDING W/ALTERED
CLOTTING/RENAL
IMPAIRMENT/ACIDOSIS/HYPERTHERMIA/HEPTAHYDRATE/RAPID/WEAK
PULSE/COMA/DEATH.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE
ARTIFICIAL RESPIRATION. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY
& SUPPORTIVELY. SKIN: WASH W/SOAP OR MILD DETERGENT & PLENTY OF
WATER FOR 1 5-20 MINS. EYES: FLUSH W/PLENTY OF WATER OR NORMAL
SALINE FOR 15-20 MINS. INGESTION: DON'T INDUCE VOMITING. OBTAIN
MEDICAL ATTENTION IN ALL CASES.

Extinguishing Media:DRY CHEMICAL, CO2, HALON, WATER SPRAY OR FOG,
STANDARD FOAM
Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE.
KEEP UPWIND.

Spill Release Procedures:ABSORB W/VERMICULITE OR OTHER SUITABLE
MATERIAL. PLACE IN A SUITABLE CONTAINER (PLASTIC), FOR LATER
DISPOSAL.

Other Precautions:AVOID BREATHING VAPORS OR DUSTS.

Respiratory Protection:USE CHEMICAL CARTRIDGE RESPIRATOR OR GAS MASK
W/ORGANIC VAPOR CANISTER (CHIN-STYLE FRONT/BACK MOUNTED) W/FULL
FACEPIECE. USE TYPE C SUPPLIED-AIR RESPIRATOR, SCBB OPERATED IN
PRESSURE-DEMAND OR OTHE RP OSITIVE MODE W/FULL FACEPIECE. SEE SUPP.
Ventilation:GENERAL DILUTION
Protective Gloves:RECOMMENDED
Eye Protection:SPLASH/DUST PROOF SAFETY GOGGLES
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING & EQUIPMENT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
RESPIRATORY PROTECTION (CONT'D): SUPPLIED-AIR RESPIRATOR W/FULL
FACEPIECE & OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE
MODE IN COMBINATION W/AUXILIARY SELF-CONTAINED BREATHING APPARATUS
OP ERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.

Boiling Pt:B.P. Text:212F
Melt/Freeze Pt:M.P/F.P Text:32F
Vapor Pres:14
Vapor Density:0.7
Spec Gravity:1
Evaporation Rate & Reference:(ETHER = 1) >1
Solubility in Water:COMPLETE

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS: 1,10-PHENANTHROLINE. ALKALIES: ARSENIC TRIOXIDE &
SODIUM NITRATE WHICH CREATE A COMBUSTIBLE MIXTURE
Stability Condition to Avoid:HEAT OR FLAME
Hazardous Decomposition Products:TOXIC OXIDES OF SULFUR

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.